Well you sure can paint an acoustic guitar, and as mentioned before you have to carefully remove the previous finish.
However, you will certainly change the sound, that is something you have to take into consideration. I’m not saying your guitar is going to sound bad, just that you will change the sound, for better or for worse is for the player to decide.
The whole idea with “solid tops” is for the top on the guitar to be able to vibrate more and create better and warmer resonance. The methoods to achieve this are probably as many as there are manufacterers, so I don’t think there are a universal reciepie for this.
I’ve seen that most of the luthiers do apply many layers of lacqure/finish solvent of your choice, in many many superthin layers (10-15) because if you spray it to thick, you take away the ability for the wood that vibrate according to the frequencies you create while playing.
I would check out “www.stewmac.com” for solvents, polishing products and further information regarding the subject. Another great place is “www.projectguitar.com”.
My tip would be to aproach all the different steps very very gentle, be careful sanding it down, and polishing it,and do not paint too thick, instead apply different superthin layers.
Good Luck
have a good one
hope that helped some
//Ken1